Controlled Radical Polymerization of Acrylates Regulated by Visible Light
نویسندگان
چکیده
منابع مشابه
Visible Light-Induced Atom Transfer Radical Polymerization for Macromolecular Syntheses
Visible light-induced atom transfer radical polymerization (ATRP) of vinyl monomers are examined by using various photocatalysts systems including Type I and Type II photoinitiators, dyes, dimanganese decacarbonyl and semiconducting photocatalysts. The influence of various experimental parameters on the polymerization such as type of light sources and photocatalyts, and concentration of metal c...
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Atom transfer radical polymerization (ATRP) was applied to homo and block copolymerization of vinyl monomers methacrylates, acrylates, and styrene with iron (FeCl2.4H2O) as the transition metal in most cases. As complexing ligand either a commercially available ligand (triphenyl phosphine) (PPh3) or synthetic aliphatic amines were used. As initiators, methyl 2-bromopropionate, ethyl 2-bromoisob...
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ژورنال
عنوان ژورنال: ACS Macro Letters
سال: 2014
ISSN: 2161-1653,2161-1653
DOI: 10.1021/mz500242a